Question

For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rᴀ₀ is invariant with total pressure. The rate controlling step is

a.

surface Kc/(1 + Tₛ) reaction between absorbed A and B in the gas phase.

b.

surface reaction between absorbed A and absorbed B.

c.

surface reaction between A in the gas phase and absorbed B.

d.

desorption of C.

Answer: (d).desorption of C.

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Q. For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rᴀ₀ is invariant with total pressure. The rate controlling step is

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